New quaternary ammonium salts derived from cardanol and their use as phase transfer catalyst
نویسندگان
چکیده
منابع مشابه
Quaternary ammonium amalgams as Zintl ion salts and their use in the synthesis of novel quaternary ammonium salts.
dodecapeptide 5 does not seem to follow this trend, which may suggest that secondary interactions exist between the terpenoid and peptide moieties. Although we still need to perform many experiments to develop a reliable mechanistic model to explain the observed phenomenon, our preliminary observations show an interesting potential in this area and investigation along this line is in progress i...
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A novel class of tartaric acid-derived N-spiro quaternary ammonium salts was synthesised starting from known TADDOLs. These compounds were found to catalyse the asymmetric α-alkylation of glycine Schiff bases with high enantioselectivities and in good yields.
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[reaction: see text] The catalytic enantioselective electrophilic fluorination promoted by quaternary ammonium salt from cinchonine as a phase-transfer catalyst is described. Treatment of beta-keto esters with N-fluorobenzenesulfonimide as the fluorine source under mild reaction conditions afforded the corresponding alpha-fluoro beta-keto esters in exellent yields with good to moderate enantiom...
متن کاملCrystal structures of three new N-halomethylated quaternary ammonium salts
In the crystals of the title N-halo-methyl-ated quaternary ammonium salts, C19H23IN(+)·I(-), (I) [systematic name: N-(4,4-di-phenyl-but-3-en-1-yl)-N-iodo-methyl-N,N-di-methyl-ammonium iodide], C20H25IN(+)·I(-), (II) [systematic name: N-(5,5-di-phenyl-pent-4-en-1-yl)-N-iodo-methyl-N,N-di-methyl-ammonium iodide], and C21H27IN(+)·I(-), (III) [systematic name: N-(6,6-di-phenyl-hex-5-en-1-yl)-N-iodo...
متن کاملMicrowave synthesis of quaternary ammonium salts.
The microwave synthesis of several quaternary ammonium salts is described. The synthesis provides comparable or better yields than published methods with reduced reaction times and in the absence of solvent.
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ژورنال
عنوان ژورنال: Journal of the Brazilian Chemical Society
سال: 2000
ISSN: 0103-5053
DOI: 10.1590/s0103-50532000000100005